Table of Contents
4.0) Safe Disposal of Radioactive Waste
Copied from the Radiation Safety Services guidance document 3.7 as published
dated 5/97 and as revised 8/97.
4.1) Radioactive Waste Management Policy
The Radiation Safety Service (RSS) processes all radioactive waste generated
at the University of Kansas. Any laboratory material and/or labware considered
a waste and brought into contact with or is initially considered contaminated
by radioactive materials must finally be disposed of by the RSS. Waste
is considered any material or component for which the authorized user foresees
no further use. All radioactive sources must be ordered through the RSS,
and in turn, all waste generated from the experimental use of radioactive
sources must be prepared for the RSS. Users are not authorized to discard
any radioactive waste to the sewer, vent, or by violating mandated procedures,
to regular trash.
RSS is committed to limiting and restricting the release of radioactive
materials to the environment. Only those materials that were designed to
be released to the environment (air and sewer) should be disposed by venting
to the atmosphere or releasing to the sewer. Dilution is not viewed as
a true means of disposal. Extensive control is placed upon any experiment
generating volatile wastes. In addition, ALARA goals have been adopted
to encourage the elimination of any release, and to attempt to reduce the
exposure to the public.
Each specific laboratory that generates the waste must manage radioactive
waste generated at the University of Kansas. Authorized users are responsible
for completing the appropriate records as specified by the RSS and for
preparing all wastes for transfer to the RSS for disposal. RSS personnel
transport all radioactive waste (solid, liquid, scintillation vials, etc.)
in approved containers with the proper packaging and shipping manifests
to either Burt Hall or Haworth Hall. Waste is segregated, packaged, and
compacted as needed in the radioactive waste processing facility in Burt
Hall.
4.2) Radioactive Waste Minimization Program
The radioactive waste minimization program addresses process changes
that can be made to reduce or eliminate radioactive wastes, methods to
minimize the volume of regulated radioactive wastes through better segregation
of materials, and by substitution of nonhazardous materials for hazardous
materials. The goal of the radioactive waste minimization plan is to minimize
the present and future concerns to the human health and environment by
reducing or eliminating radioactive wastes as much as is economically practicable,
and by pursuing the best radioactive waste management method that is available.
Radioactive waste minimization includes reviewing the use of the materials
for alternative methods, improved administrative controls, source reduction
(material substitution, practice modifications, inventory management),
volume reduction, and alternative treatment and disposal methods.
4.3) Radioactive Waste Storage
Although the user is able to determine the continued usability of radioactively
contaminated material and components, radioactive waste storage in the
laboratory is not authorized. Designated containers are placed in the laboratory
by the RSS for accumulating radioactive wastes. These containers are usually
fiber drums for solid and scintillation vial radioactive wastes, marked
three and one-half gallon pails for limited generation of scintillation
vial radioactive waste, and one gallon plastic/glass jugs for liquid radioactive
wastes. Secondary containers are required for liquid radioactive wastes
that are accumulating in the laboratory. Only fiber drums and pails provided
by the RSS may be placed on the floor. All other radioactive waste containers
must be placed on benchtops. Users are required to complete the required
documentation describing the radioactive waste and to prepare the waste
for RSS transfer when the container is filled.
4.4) Evaluation of Waste Activity
A researcher is responsible for verifying that the conditions of the
permit and that the regulations pertaining to the University's license
are completely followed. To do so, researchers must often evaluate dose
rates, safety precautions, and activity levels from the proposed experimental
procedures to gain the necessary information before performing the experiment.
In the same way that estimations must be made from these procedures, waste
disposal requires that determinations be made either before the waste is
generated or at the time of generation. This evaluation is required not
only to make sure that regulatory levels are not exceeded, but also that
current practices conform to University policies.
Evaluations of this nature do not have to be extensive. Representative
samples from different kinds of processes should be analyzed to document
activities from each particular waste stream. If one can differentiate
between background and the sample (greater than twice background) the sample
has detectable activity. For liquid waste the easiest approach to the problem
is to release only tertiary rinses to the sanitary sewer. Tertiary rinses
do not usually have detectable activity. The waste material, and primary
and secondary rinses, usually have activities that exceed detectable activities.
Tertiary rinses may be discarded.
Eliminating the release of radioactive materials to the sanitary sewer
seems prudent since the sanitary sewer was not designed for such disposal,
dilution is not a true means of disposal, and disposal by several licensed
facilities may lead to increased levels in the sludge at treatment facilities.
In addition, there is some indication that neutralization tanks may concentrate
or at least become contaminated with the activity that has been released
from the laboratories. Tanks do exist in Haworth and Malott.
4.5) Segregation
Prudent practice requires the segregation of radioactive waste as specified
by the RSS. Radioactive materials with half-lives less than 60 days that
contain no other hazardous chemicals are disposed by decay. The materials
in any given container are kept by the RSS for no less than twenty half
lives before disposal. Waste costs are often based upon the isotopes that
are present and the activity in the waste.
4.6) Shipping Manifests/Recordkeeping
The shipping manifest and waste summary sheet serves two purposes. The
first purpose is to document the radioactive waste activity that is removed
from the laboratory. This documentation includes the kinds of radioactive
waste containers that are removed from the laboratory, as well as the source
location for the activity. The second purpose is to fulfill the transportation
requirements.
4.7) Specific Types of Radioactive Waste
4.7.1) Solid/Dry Waste
Solid/dry wastes are generated from routine radiation laboratory procedures.
These wastes include gloves, absorbent paper, glassware, and other routine
labware used in the laboratory that may have come in contact with radiation.
Solid wastes are to be placed into 20 gallon fiber drums as specified and
supplied by RSS. Segregation is required by isotope. The RSS transfers
the fiber drums to Burt Hall where the contents are repackaged into 55
gallon drums for decay in storage and/or disposal.
4.7.2) Aqueous Waste
Aqueous wastes are generated from routine radiation laboratory procedures.
These wastes are collected into one gallon plastic/glass containers provided
by RSS. Liquid wastes are transferred to RSS for decay in storage and/or
disposal.
4.7.3) Scintillation Mixed Wastes
Scintillation mixed wastes are generated from determinations of radioactivity
made by placing laboratory samples in vials containing scintillation fluid.
Following analysis, the vials containing waste scintillation fluids are
placed directly into twenty gallon fiber drums or three and one-half gallon
pails in the laboratory. The RSS transfer the fiber drums and pails to
Burt, and the contents are repackaged in fifty-five gallon drums for shipment.
The drums are shipped on a routine quarterly schedule by a commercial broker
to a licensed facility for final disposal by energy recovery.
4.7.4) Solvent Mixed Waste
Solvent mixed waste, (hazardous chemical and radioactive), waste which
is regulated under both the EPA and NRC/Agreement State, may be generated
in a very limited and restricted manner. Since the disposal depends upon
the availability of treatment facilities, the RSS wishes to facilitate
necessary research while limiting the generation of mixed waste by encouraging
substitution and by promoting the active engagement of the users in reducing
quantities of mixed waste. Researchers are required to verify that nonhazardous
components will be substituted for hazardous components whenever possible,
and that the generation of mixed waste will be eliminated whenever possible.
Satellite accumulation areas exist in laboratories where mixed wastes
initially accumulate. The waste container is located near the point of
generation, and is under the control of the operator of the process generating
the waste. The container is marked with the words "Hazardous Waste." Mixed
waste is routinely collected and shipped to a licensed treatment/disposal
facility.
4.7.5) Animal/Biological Waste
RSS approval must be received before the generation of any radioactive
animal or biological wastes. Such wastes are to be packaged according to
RSS procedures. Waste are transferred to RSS for disposal.
4.8) Disposal Capacity
4.8.1) Commercial Disposal
Contractors, possessing the requisite expertise, facilities, and legal
right to transport and dispose of low-level radioactive waste in a safe
and efficient manner and by all valid and applicable federal, state, and
city regulations, provide waste disposal services to commercial disposal
facilities. Solid wastes are compacted and prepared for shipment by the
RSS. Commercial shipments are very costly. ($2500 drum)
Several basic categories of radioactive waste are produced at the University
of Kansas. These categories are determined by the mandates of federal regulatory
agencies, the cost to the University and the facilitation of disposal.
4.9) General Procedures
4.9.1) Accumulation
Accumulation of radioactive wastes within laboratories will be under
standardized conditions so that all personnel including those of housekeeping
and facilities operation will be able to recognize the waste containers.
To this end all radioactive waste will be stored in special fiber drums
provided by the RSS. The conditions for packaging within the drums will
depend upon the category of waste as described below. In some cases it
may be inconvenient to store in the drum small volumes of waste to which
materials are still being added. In such cases, a clearly labeled box or
container located on a bench area reserved for "restricted" work
may be approved by the RSS. However, such boxes and/or containers may not
be placed on the floor. Liquid wastes must be stored in gallon containers
provided by the RSS or as specified by the RSS. Liquid wastes must be in
a secondary container which could catch the wastes if the primary container
were to break unless the primary container is unbreakable.
4.9.1.1) Documentation Requirements for Drums and Containers
The prerequisites for any drum exchange or waste pickup are that the
waste be packaged as requested and that a waste description summary accompany
the waste container. This summary (WD-IV) must have the following information.
4.9.2) Categories of Waste
4.9.2.1) Category I - Deregulated Vials
a)scintillation vials with only H-3 and C-14.
b)normally at concentrations no greater than used in liquid scintillation
counting systems.
c)Close vial lids tightly.
d)Place glass or plastic vials directly into the drum.
e)Keep lid on the drum between uses - does not have to be lever locked.
f)When drum is full and the record keeping is complete, call the RSS.
4.9.2.2) Category II - Regulated Vials
a)scintillation vials other than H-3 and C-14.
b)normally at concentrations no greater than used in liquid scintillation
counting systems.
c)Close vial lids tightly.
d)Place glass or plastic vials directly into the drum.
e)Keep lid on the drum between uses - does not have to be lever locked.
f)When drum is full and the record keeping is complete, call the RSS.
4.9.2.3) Category III - Dry Solid Waste with Half-Lives Less Than 60 days
a)Absolutely no liquids of any type.
b)All needles, razor blades, and other sharp objects must be placed
in a clearly labeled container segregated from all other waste.
c)Keep lid on the drum between uses.
4.9.2.4) Category IV - Dry Solid Waste with Half-Lives Greater Than 60
days
a)Absolutely no liquids of any type.
b)All needles, razor blades, and other sharp objects must be placed
in a clearly labeled container segregated from all other waste.
c)Keep lid on the drum between uses.
4.9.2.5) Category V - Water Soluble or Aqueous Waste
a)No EPA-listed hazardous chemicals may be in this category.
b)No water-insoluble wastes.
c)No solids or other debris in this waste.
d)Place wastes in standard plastic gallon jugs. (Jugs may be purchased
from RSS or must be approved.)
e)Except possibly H-3 and C-14, isotopes shall not be mixed in the same
jug. (This applies to jugs in all categories, unless authorized by the
RSS.)
4.9.2.6) Category VI - Liquid Wastes not Included in Above Categories
a)An accurate description of the composition of the waste must be provided.
(Nature of all chemicals as well as the usual activity information.)
b)No solids or debris may be in this waste.
c)Place wastes in the standard jugs.
4.9.2.7) Category VII - Animals
a)Animals should be bagged.
b)Animals should be temporarily stored in a freezer. Methods of storing
other than freezing require special arrangements with the RSS.
c)Arrangements should be made with the RSS for disposal.
4.9.3) Number of Drums Needed per Laboratory
For best operation of this system, the RSS should be consulted as to
the number of drums that a particular lab might need. Obviously, a laboratory
would not need a drum for a type of waste that is not generated in that
lab.
Because many drums might be too much of a burden for a lab generating
small volumes of waste, the RSS will review proposals for consolidation
of Categories provided that acceptable packaging and labeling arrangements
can be made so that the wastes from a single drum can be sorted and segregated
by the RSS in a rapid and safe manner. Such an arrangement may be terminated
by the RSS if it fails to meet requirements in practice.
Experience indicates that shared drums lead to problems in record keeping
and in responsibilities for the wastes.
Drums should be placed in locations where they will not need to be moved
frequently.
4.9.4) Pick Up Schedules
When a container has been completely filled, and the paperwork has been
completed, a pickup should be scheduled with the RSS. Contact 864-4089.
New radioactive waste containers, drum liners, and plastic/glass bottles
are provided by the RSS.
4.10) Radiation Generating Devices
Authorization from RSS must be granted to any authorized user prior
to transferring a radiation generating device to another laboratory or
institution, or to disposing of the unit. RSS will certify that any radiation
generating device to be used for parts or to be disposed of has been rendered
fully inoperative and that it contains no radioactive sources before it
is approved for disposal. RSS will also confirm that any radiation generating
device to be used for parts or to be disposed of has had all labels and
markings removed, and that appropriate release surveys have been performed
before it is approved for disposal. If the unit is to be transferred to
another laboratory or institution, RSS will verify that the recipient is
appropriately authorized to receive the radiation generating device.